An NVMe SSD can replace a SATA system drive only when the PC supports the new drive and can boot from it. Moving visible files is not enough.

Choose a whole-disk clone to include EFI/System Reserved, Windows, and recovery partitions. If the NVMe drive is smaller, the used data and all necessary partitions must fit. The destination NVMe will be overwritten.
Check that firmware detects the NVMe drive, that the system partition was included, and that the boot mode matches the cloned disk. A USB NVMe enclosure may let you clone but may not represent the final internal boot path.
Choose the SATA SSD as source and the internal NVMe SSD as destination. Verify both model names carefully before you click Proceed.
Step 1. Connect the destination drive. Open Tools and utilities in Qiling Disk Master and choose Disk/Partition clone. For a boot-drive replacement, choose the entire disk rather than only C:.

Step 2. Select the existing system disk as the source. Compare its model, capacity, and partition map; include the boot and recovery partitions. Click Next.

Step 3. Select the new drive as the destination by model and capacity, then click Next. Cloning overwrites this disk, so move its useful files elsewhere first.

Step 4. Inspect the source-to-destination layout. Ensure the required partitions fit; use Optimize for SSD when the destination is an SSD and that option is available. The screenshot illustrates the preview controls; verify your own whole-disk partition map.

Step 5. Click Proceed. Read any overwrite warning and confirm only after rechecking the target disk. Keep both drives connected until the progress screen reports completion; then boot-test the destination before reusing the source.

Will NVMe always make Windows feel faster? It may improve large transfers, but many everyday tasks are less sensitive once you already use an SSD.
Can I leave both system drives installed? Yes, after confirming boot priority, though disconnecting the old one for the first test simplifies diagnosis.
NVMe migration requires both a compatible slot and a complete bootable transfer. Test the new boot entry before changing the SATA source disk.