Most Windows disks carry one EFI system partition. A refurbished or dual-boot machine can carry two or three, and each holds its own boot loader. Copying the wrong one produces a drive that refuses to start.
This guide explains how the extra partitions appear, how to map every boot entry before the copy, and how to clone the whole disk while keeping the boot order intact.
Windows boots from the EFI partition that the firmware entry points to, not necessarily the first one on the disk. That is why a copy can look complete and still fail to start.

Run the mapping from an elevated prompt while the machine still boots. Once the drive is in the new position, the disk numbers shift and the old notes become harder to interpret.

A whole-disk clone keeps the layout exactly as it is, which is the safest choice with several boot partitions. A partition-level copy is the option that creates the confusion in the first place.
Qiling Disk Master copies the disk block by block, so every EFI partition and its contents arrive on the new drive unchanged. Attach the target through USB or an internal bay, then run the task from Windows.
Watch the video tutorial below to clone the drive step by step with Qiling Disk Master.
Step 1. Open Qiling Disk Master, choose Clone, and then select Disk Clone.

Step 2. Select the disk that holds all the EFI partitions as the source and click Next.

Step 3. Select the target disk as the destination and confirm that its data will be replaced.

Step 4. Check that every EFI and recovery volume is ticked, then tick Optimize for SSD if the target is solid state.

Step 5. Click Proceed, wait for the copy to finish, and shut the machine down before you move the drive.

Duplicate entries usually appear because the firmware keeps the old device path. The repair command bcdboot C:\Windows /s S: /f UEFI rewrites the loader on the correct EFI partition.
Yes. A disk-level copy takes all partitions, including the ones Windows does not mount.
Only if no boot entry uses it. Check with bcdedit first, then keep a backup of the disk.
The firmware entry still points at the old disk number. Remove the extra entry or rebuild the loader.
No, not when several partitions boot. Use a whole-disk clone so the layout and the entries stay matched.
It can. A disk change alters the measured boot state, so keep the recovery key within reach.
A multi-partition boot disk is harder to rebuild than a normal one. Make a full system image first so the layout can be restored if the copy goes wrong.
Watch the video tutorial below to back up Windows and restore it if the clone fails.
Step 1. Open Qiling Disk Master and select System Backup to include the boot partitions.

Step 2. Save the image to a drive other than the target disk and start the backup.

Step 3. Click Proceed to start the system backup and wait patiently until it finishes. You can also tick Shut down the computer when the operation is completed to power off automatically.

Step 4. If the cloned drive will not start, restore the image to the original disk and check the boot entries again.

Multiple EFI partitions are a layout problem, not a cloning problem. Map every FAT32 boot volume and its firmware entry while the machine still starts, keep them all in the copy, and remove the old drive before the first boot. If an entry points at the wrong disk, rebuild the loader with bcdboot and delete the stale firmware record.
For more on boot structure, see How to Clone Windows 11 with the System Reserved Partition, How to Clone the Windows Recovery Partition to a New SSD, How to Clone an MBR Disk to a GPT SSD, and How to Clone Only the OS Partition to a New SSD.