Moving Windows from a small SSD to a large hard drive sounds backwards, but it is common when capacity matters more than speed and the SSD is needed elsewhere.
This guide covers the capacity check, the settings that differ on a mechanical target, and how to keep the copy bootable.
Expect a slower machine after the switch. The clone preserves the installation, but it cannot preserve SSD responsiveness.

Alignment still matters even on a mechanical drive. A partition that starts on a 4K boundary avoids unnecessary read-modify-write cycles.

Do not delete the SSD partitions until the copy has booted. The original drive is the fastest rollback if the mechanical target fails.
Qiling Disk Master copies the full disk with its boot and recovery partitions. The tool adapts to the slower target without changing the layout.
Step 1. Open Qiling Disk Master, choose Clone, and then select Disk Clone.

Step 2. Select the SSD as the source and click Next.

Step 3. Select the HDD as the destination and confirm that its data will be replaced.

Step 4. Review the partitions, keep the boot and recovery volumes, and enlarge the system volume if space allows.

Step 5. Click Proceed, wait for the copy to finish, then shut down and set the HDD as the boot device.

If the copy will not boot, the boot entry is the likely cause rather than the disk. Cloned Drive Wont Boot Fix covers the repair steps.
Yes when the whole disk is cloned with its boot and recovery partitions.
Yes. Boot time and app loading return to mechanical drive levels, though capacity improves.
Windows schedules it automatically. A manual pass is only needed after a very large data move.
Only if the used space fits. Shrink the system partition before the clone and check every volume.
Yes on the same hardware. Only a motherboard change triggers a new activation.
Before changing drives or partitions, create a full system backup. Qiling Disk Master creates an image you can restore from.
Step 1. Open Qiling Disk Master and select System Backup to include Windows and the boot partitions.

Step 2. Save the image to a drive other than the target disk and start the backup.

Step 3. Click Proceed to start the system backup and wait patiently until it finishes. You can also tick Shut down the computer when the operation is completed to power off automatically.

Step 4. If the copy will not start, restore the image to a spare drive and boot from it.

Cloning an SSD to an HDD trades speed for capacity. Confirm the HDD is larger than the used data, keep the partition style and SATA mode unchanged, and suspend BitLocker before the copy. Clone the whole disk so the boot files travel with Windows, then set the HDD first, extend the system volume into the free space, and keep the SSD aside as a rollback.
For more on drive changes, see How to Clone a Hard Drive to a Larger Hard Drive, 4K Alignment When Cloning an SSD, Cloned Drive Wont Boot Fix, and How Long Does a Disk Clone Take.